Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkyl alkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields. Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system
A new facile synthesis of α-dicarbonyl compounds by oxidation of alkynes with Mo(VI) peroxocomplex promoted by mercuric acetate
Ballistreri, F. P.;Failla, S.;TOMASELLI, Gaetano;
1986-01-01
Abstract
Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkyl alkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields. Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing systemFile in questo prodotto:
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