A new chiral Mn-salen catalyst, functionalized with a long aliphatic chain and a choline group, able to act as surfactant catalyst for green epoxidation in water, is here described. This catalyst was employed with a commercial surfactant (CTABr) leading to a nanoreactor for the enantioselective epoxidation of some selected alkenes in water, using NaClO as oxidant. This is the first example of a nanoreactor for enantioselective epoxidation of non-functionalized alkenes in water.
A New Mn–Salen Micellar Nanoreactor for Enantioselective Epoxidation of Alkenes in Water
Ballistreri, Francesco;Toscano, Rosa;Amato, Maria;Pappalardo, Andrea;Gangemi, Chiara;PUGLISI, ROBERTA;Trusso Sfrazzetto, Giuseppe
2018-01-01
Abstract
A new chiral Mn-salen catalyst, functionalized with a long aliphatic chain and a choline group, able to act as surfactant catalyst for green epoxidation in water, is here described. This catalyst was employed with a commercial surfactant (CTABr) leading to a nanoreactor for the enantioselective epoxidation of some selected alkenes in water, using NaClO as oxidant. This is the first example of a nanoreactor for enantioselective epoxidation of non-functionalized alkenes in water.File in questo prodotto:
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