Sensing of Chemical Warfare Agents is today an important target, mainly due to the international scenario. Here a new approach, based on supramolecular multi-topic recognition of dimethyl methylphosphonate, a simulant of Chemical Warfare agents, is reported. These receptors, based on metal-salen complexes, combine their abilities to establish Lewis Acid-Base interactions and hydrogen bonds and pave the way for the realization of a new class of supramolecular sensors for the non-covalent recognition of Chemical Warfare Agents simulants.

Supramolecular recognition of CWAs simulant by metal-salen complexes: the first multi-topic approach

Trusso Sfrazzetto, Giuseppe
;
Pappalardo, Andrea;Puglisi, Roberta;Gulino, Antonino
2018-01-01

Abstract

Sensing of Chemical Warfare Agents is today an important target, mainly due to the international scenario. Here a new approach, based on supramolecular multi-topic recognition of dimethyl methylphosphonate, a simulant of Chemical Warfare agents, is reported. These receptors, based on metal-salen complexes, combine their abilities to establish Lewis Acid-Base interactions and hydrogen bonds and pave the way for the realization of a new class of supramolecular sensors for the non-covalent recognition of Chemical Warfare Agents simulants.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/335448
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