Aromatic and aliphatic thiols are oxidized in acetonitrile at 20 C by hydrogen peroxide in the presence of methyltrioxorhenium as thecatalyst to yield the corresponding sulfonic acids in high isolated yields (85–94%).
Selective and mild oxidation of thiols to sulfonic acids by hydrogen peroxide catalyzed by methyltrioxorhenium
BALLISTRERI, Francesco Paolo;TOMASELLI, Gaetano;TOSCANO, Rosa Maria
2008-01-01
Abstract
Aromatic and aliphatic thiols are oxidized in acetonitrile at 20 C by hydrogen peroxide in the presence of methyltrioxorhenium as thecatalyst to yield the corresponding sulfonic acids in high isolated yields (85–94%).File in questo prodotto:
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