A novel class of polymers was obtained by insertion of dirhodium(II, II) metal systems into a methacrylate backbone; the synthesis was realized by free radical polymerization of an appropriate methacrylate-functionalized dirhodium polymer precursor, namely [Rh-2(form)(2)(MA-COO) (2)] (form = N, N'-di-p-tolylformamidinate) (MA-COO = 2-(methacroyloxy) ethyl-phthalate), with methylmethacrylate (MMA); the new copolymers, in solution, show reversible CO-absorption, connected to the axial reactivity of dirhodium(II, II) species.
Redox-active dirhodium(II,II) species covalently entrapped into a methylmethacrylate backbone
MINEO, PLACIDO;
2005-01-01
Abstract
A novel class of polymers was obtained by insertion of dirhodium(II, II) metal systems into a methacrylate backbone; the synthesis was realized by free radical polymerization of an appropriate methacrylate-functionalized dirhodium polymer precursor, namely [Rh-2(form)(2)(MA-COO) (2)] (form = N, N'-di-p-tolylformamidinate) (MA-COO = 2-(methacroyloxy) ethyl-phthalate), with methylmethacrylate (MMA); the new copolymers, in solution, show reversible CO-absorption, connected to the axial reactivity of dirhodium(II, II) species.File in questo prodotto:
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