The thermal behavior of the Fe(II) iodide mixed complexes with 1,10-phenanthroline and 4,7-disubstituted phenanthrolines in nitrogen atmosphere is investigated. In order to determine to what extent small changes in ligand field symmetries influence the "activation energy" E{black star}a, this energy is determined. The results are discussed in relation to the changes of the σ and π bonds.
Thermal decomposition of metal complexes. II. Mixed complexes of iron(II) iodide with 1,10-phenanthroline, and 4,7-disubstituted-1,10-phenanthrolines
BONOMO, Raffaele;RIZZARELLI, Enrico;
1974-01-01
Abstract
The thermal behavior of the Fe(II) iodide mixed complexes with 1,10-phenanthroline and 4,7-disubstituted phenanthrolines in nitrogen atmosphere is investigated. In order to determine to what extent small changes in ligand field symmetries influence the "activation energy" E{black star}a, this energy is determined. The results are discussed in relation to the changes of the σ and π bonds.File in questo prodotto:
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