ESCA has been used to monitor the changes in the surface composition of polystyrene and 2-(2-hydroxy-3-vinyl-5-methylphenyl)-benzotriazole/styrene (HVB/sty) copolymers during uv (λ > 300 nm) irradiation in air. Oxygen uptake in the surface is more rapid for the copolymers and is dependent on the benzotriazole content of the surface. On extended exposure the nitrogen content in the surface increases. The behaviour of the HVB in the surface is indicative of photo-sensitisation and not of photo-stabilisation.

A preliminary investigation of the surface photo-oxidation of copolymers of styrene and 2-(2-hydroxy-3-vinyl-5-methylphenyl)-benzotriazole

RECCA, Antonino;BOTTINO, Francesco;POLLICINO, Antonino
1986-01-01

Abstract

ESCA has been used to monitor the changes in the surface composition of polystyrene and 2-(2-hydroxy-3-vinyl-5-methylphenyl)-benzotriazole/styrene (HVB/sty) copolymers during uv (λ > 300 nm) irradiation in air. Oxygen uptake in the surface is more rapid for the copolymers and is dependent on the benzotriazole content of the surface. On extended exposure the nitrogen content in the surface increases. The behaviour of the HVB in the surface is indicative of photo-sensitisation and not of photo-stabilisation.
1986
XPS
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/11146
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