The cycloaddition of nitrones (4) to propene, followed by sequential treatment with methyl trifluoromethanesulfonate, H-2-Pd/C, and m-chloroperbenzoic acid, is shown to provide a general method for the preparation of a variety of volatile streptomyces lactones.
The cycloaddition of nitrones (4) to propene, followed by sequential treatment with methyl trifluoromethanesulfonate, H-2-Pd/C, and m-chloroperbenzoic acid, is shown to provide a general method for the preparation of a variety of volatile streptomyces lactones.
A NEW SYNTHESIS OF STREPTOMYCES LACTONES BY 1,3-DIPOLAR CYCLOADDITION
CHIACCHIO, Ugo;RESCIFINA, Antonio;
1993-01-01
Abstract
The cycloaddition of nitrones (4) to propene, followed by sequential treatment with methyl trifluoromethanesulfonate, H-2-Pd/C, and m-chloroperbenzoic acid, is shown to provide a general method for the preparation of a variety of volatile streptomyces lactones.File in questo prodotto:
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