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EnglishThe photochemistry of ketoprofen (KPF), 2-(3-benzoylphenyl)propionic acid, has been studied in aqueous solutions by time resolved (picosecond and nanosecond) spectroscopic techniques. Excited-state calculations were performed. The overall reactivity of the molecule was rationalized within a scheme in which the lowest triplet state can undergo intramolecular electron transfer and photoionization. The main pathway for the;formation of the decarboxylated photoproducts was shown to involve intramolecular electron transfer and to pass through triplet biradicals. RI Monti, Sandra/B-9272-2009; Sortino, Salvatore/E-4684-2011
| Titolo: | Photochemistry of 2-(3-benzoylphenyl)propionic acid (ketoprofen) .1. A picosecond and nanosecond time resolved study in aqueous solution |
| Autori interni: | |
| Data di pubblicazione: | 1997 |
| Rivista: | |
| Citazione: | Photochemistry of 2-(3-benzoylphenyl)propionic acid (ketoprofen) .1. A picosecond and nanosecond time resolved study in aqueous solution / Monti S; Sortino S; DeGuidi G; Marconi G. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS. - ISSN 0956-5000. - 93:13(1997), pp. 2269-2275. |
| Handle: | http://hdl.handle.net/20.500.11769/13469 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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