The chemical phenomenology which occurs in polystyrene films bombarded with low doses 100 keV He+ ions has been investigated by infrared spectroscopy. The results obtained show that the polymer is rapidly transformed into a different chemical compound consistent with high cross-linking as indicated by low solubility in CHCI3. The I.R. finding is in agreement with XPS findings and indicates that the observed phenomenology occurs via a mechanism which eliminates the electronic “π” system of the phenyl ring and gives rise to alkene-type bonding.
Titolo: | Primary chemical events in ion bombarded polystyrene films: An infrared study |
Autori interni: | |
Data di pubblicazione: | 1986 |
Rivista: | |
Handle: | http://hdl.handle.net/20.500.11769/15280 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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