Degassing driving crystallization of plagioclase phenocrysts in lava tube stalactites on Mount Etna (Sicily, Italy)

Basaltic lava flows can form tubes in response to the cooling of the outer surface. We collected lava stalactites (frozen lava tears) and sampled lava from the ceilings of three lava tubes on Mount Etna. Comparison of the petrographic characters between ceiling lavas and relative stalactites reveals surprising differences in the groundmass textures and crystal compositions. Major and trace element contents in stalactites show only a slight increase in alkali and SiO2 compared to ceiling lava, whereas significant differences exist in composition and textures between plagioclases within the ceiling lava and those within the stalactites, being in the last case definitively more An-rich. We advance the hypothesis that the high temperature reached in the cave caused the exsolution of the volatiles still trapped in the dripping melt. The volatiles, mainly H2O, formed bubbles and escaped from the melt; such a water-loss might have promoted the silicate polymerization in the stalactites resulting in the growth of An-rich plagioclase phenocrysts. Our results have important implications: in fact plagioclase phenocrysts are usually associated with intratelluric growth and are often considered as the main petrologic evidence for the existence of a magma chamber. The textural and chemical features of plagioclases in stalactites prove that phenocryst growth in syn to post-eruptive conditions is plausible and clearly explains the relatively low viscosity of many phenocryst-rich lava flows on Mount Etna, as well as on many other volcanoes around the world. Therefore, we can conclude that plagioclase phenocrysts cannot exclusively be considered as having originated within a magma chamber.