The photoelectron spectra of some cyclopentadienyI derivatives of uranium(IV) and thorium(IV), namely (C5H5)3 ThCl, (C5H5)3 UCl, (C5 H4 CH3)3 ThCl, (C5 H4 CH3)3 UCl, (C5 H4 CH3)3 UBr and (C5 H4 CH3 )3 UBH4, are reported the metal 5f ionization has been detected in all the uranium derivative spectra and a simple molecular orbital scheme qualitatively accounts for the number and position of the observed low energy bands.

Photoelectron spectroscopy of f-element organometallic compounds II. Tricyclopentadienyl derivatives of uranium(IV) and thorium(IV)

CILIBERTO, Enrico;
1976

Abstract

The photoelectron spectra of some cyclopentadienyI derivatives of uranium(IV) and thorium(IV), namely (C5H5)3 ThCl, (C5H5)3 UCl, (C5 H4 CH3)3 ThCl, (C5 H4 CH3)3 UCl, (C5 H4 CH3)3 UBr and (C5 H4 CH3 )3 UBH4, are reported the metal 5f ionization has been detected in all the uranium derivative spectra and a simple molecular orbital scheme qualitatively accounts for the number and position of the observed low energy bands.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11769/18019
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