Herein, we exploit the induction of chirality by chiral Zn(II) Schiff-base complexes, followed by their spontaneous dissociation in aqueous solution, providing for the first time a possibility of overcoming the template removal steps, to demonstrate memorization of chirality in porphyrin hetero-aggregates.
Chirality of self-assembled achiral porphyrins induced by chiral Zn(II) Schiff-base complexes and maintained after spontaneous dissociation of the templates: a new case of chiral memory
Gaeta M;Oliveri IP;FRAGALA', Maria Elena;FAILLA, Salvatore;D'URSO, ALESSANDRO;DI BELLA, Santo;PURRELLO, Roberto
2016-01-01
Abstract
Herein, we exploit the induction of chirality by chiral Zn(II) Schiff-base complexes, followed by their spontaneous dissociation in aqueous solution, providing for the first time a possibility of overcoming the template removal steps, to demonstrate memorization of chirality in porphyrin hetero-aggregates.File in questo prodotto:
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