A marked chemiresistive behavior is revealed in a nanostructured material obtained by spin-coating a solution of a bis(salycilaldiminato) Zn(II) Schiff-base (ZnSB) complex. The resulting submicron 2D network exhibits reversible changes in absorbance and resistance under the cycles of absorption and desorption of a volatile amine. These results are explained in terms of a Lewis donor-acceptor interaction between the ZnSB (acceptor) and the chemisorbed amine (donor). The 2D network of ZnSB was employed as a sensing element to fabricate a low-cost device for the volatile amines detection, showing promising results for food spoilage detection. Published by AIP Publishing.
Low-cost chemiresistive sensor for volatile amines based on a 2D network of a zinc(II) Schiff-base complex
MIRABELLA, SALVATORE;Oliveri IP;RUFFINO, FRANCESCO;MACCARRONE, Giuseppe;DI BELLA, Santo
2016-01-01
Abstract
A marked chemiresistive behavior is revealed in a nanostructured material obtained by spin-coating a solution of a bis(salycilaldiminato) Zn(II) Schiff-base (ZnSB) complex. The resulting submicron 2D network exhibits reversible changes in absorbance and resistance under the cycles of absorption and desorption of a volatile amine. These results are explained in terms of a Lewis donor-acceptor interaction between the ZnSB (acceptor) and the chemisorbed amine (donor). The 2D network of ZnSB was employed as a sensing element to fabricate a low-cost device for the volatile amines detection, showing promising results for food spoilage detection. Published by AIP Publishing.| File | Dimensione | Formato | |
|---|---|---|---|
|
APL Ms.pdf
solo gestori archivio
Tipologia:
Versione Editoriale (PDF)
Licenza:
Non specificato
Dimensione
1.1 MB
Formato
Adobe PDF
|
1.1 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
