The kinetics of the thermal decomposition of some binuclear and trinuclear complexes of lanthanide(III) ions with the ligand N, N′-propilenbis (salicylideniminato) Cu(II) were studied under high vacuum (2 × 10-6 mm Hg) and in isothermal conditions. The trend of E*a values of the heavier lanthanoid complexes does not fit a reliable relation with the ionic radius, while the lighter lanthanoid complexes parallel those observed in other already studied lanthanoid derivatives.
Thermal decomposition of metal complexes. IX. Polynuclear complexes of lanthanide(III) ions with a metal schiff base complex as ligand
RIZZARELLI, Enrico;
1979-01-01
Abstract
The kinetics of the thermal decomposition of some binuclear and trinuclear complexes of lanthanide(III) ions with the ligand N, N′-propilenbis (salicylideniminato) Cu(II) were studied under high vacuum (2 × 10-6 mm Hg) and in isothermal conditions. The trend of E*a values of the heavier lanthanoid complexes does not fit a reliable relation with the ionic radius, while the lighter lanthanoid complexes parallel those observed in other already studied lanthanoid derivatives.File in questo prodotto:
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