Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkyl alkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields. Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system

new facile synthesis of α-dicarbonyl compounds by oxidation of alkynes with Mo(VI) peroxocomplex promoted by mercuric acetate

Ballistreri, F. P.;Failla, S.;TOMASELLI, Gaetano;
1986

Abstract

Mercuric acetate promoted oxidation of diaryl-, dialkyl-, and aralkyl alkynes with (HMPA)MoO(O2)2 in 1,2-dichloroethane affords the corresponding α-diketones in good yields. Likewise, terminal alkynes can be converted into α-ketoaldehydes in excellent yields by using the same oxidizing system
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11769/245217
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