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English[GRAPHIC] Tall-to-tail connection of two cone calix[5]arene moieties by a rigid p-xylyl spacer affords the new exoditopic receptor 3 featuring two pi-rich cavities (assembling cores) in a centrosymmetric divergent arrangement, as established by a single-crystal X-ray analysis. H-1 NMR complexation studies of 3 with alkyldiammonium ions support the formation of discrete bis-endo-cavity complexes and/or capsular assemblies along a polymer chain (polycaps), according to the length of the connector.
| Titolo: | Inclusion networks of a calix[5]arene-based exoditopic receptor and long-chain alkyldiammonium ions RID C-4200-2008 | |
| Autori interni: | ||
| Data di pubblicazione: | 2003 | |
| Rivista: | ||
| Abstract: | [GRAPHIC] Tall-to-tail connection of two cone calix[5]arene moieties by a rigid p-xylyl spacer affords the new exoditopic receptor 3 featuring two pi-rich cavities (assembling cores) in a centrosymmetric divergent arrangement, as established by a single-crystal X-ray analysis. H-1 NMR complexation studies of 3 with alkyldiammonium ions support the formation of discrete bis-endo-cavity complexes and/or capsular assemblies along a polymer chain (polycaps), according to the length of the connector. | |
| Handle: | http://hdl.handle.net/20.500.11769/246567 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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