The interaction of a tetracationic calixarene (TAC4) with dianionic guest (BS) in water was studied with NMR, nano-ITC and ESI-MS experiments; the convergent evidence provided by these different techniques shows that the addition of a suitable guest molecule triggers the formation of a homodimeric capsule in aqueous neutral solution.
Guest-induced capsule formation based on concerted interactions in water at neutral pH
BONACCORSO, CARMELAPrimo
;SGARLATA, CARMELO;SCIOTTO, Domenico
;ARENA, Giuseppe
2010-01-01
Abstract
The interaction of a tetracationic calixarene (TAC4) with dianionic guest (BS) in water was studied with NMR, nano-ITC and ESI-MS experiments; the convergent evidence provided by these different techniques shows that the addition of a suitable guest molecule triggers the formation of a homodimeric capsule in aqueous neutral solution.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.