The first example of fluorescent chiral Zn–salen hosts, able to efficiently recognise chiral amines via non-covalent interactions, is reported here. The host–guest interactions have been characterised by 2D-NMR spectroscopy in order to elucidate the origin of enantioselectivity.
Chiral Zn–salen complexes: a new class of fluorescent receptors for enantiodiscrimination of chiral amines
PUGLISI, ROBERTA;BALLISTRERI, Francesco Paolo;TOSCANO, Rosa Maria;TOMASELLI, Gaetano;PAPPALARDO, ANDREA;TRUSSO SFRAZZETTO, GIUSEPPE
2017-01-01
Abstract
The first example of fluorescent chiral Zn–salen hosts, able to efficiently recognise chiral amines via non-covalent interactions, is reported here. The host–guest interactions have been characterised by 2D-NMR spectroscopy in order to elucidate the origin of enantioselectivity.File in questo prodotto:
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