Acid-base properties and reactivity of series of alpha-aminophosphonates has been investigated. The reaction of addition of the aminophosphonates to phenylisocyanate was used as a model reaction. The influence of steric and electronic effects of substituents at alphacarbon or nitrogen in amino group on the mechanism inversion from AdN to AdE is discussed.
Reactivity of functionalized phosphonates 1. Acid-base properties and reactivity of methyl esters of alpha-aminophosphonic acids
FAILLA, Salvatore
2002-01-01
Abstract
Acid-base properties and reactivity of series of alpha-aminophosphonates has been investigated. The reaction of addition of the aminophosphonates to phenylisocyanate was used as a model reaction. The influence of steric and electronic effects of substituents at alphacarbon or nitrogen in amino group on the mechanism inversion from AdN to AdE is discussed.File in questo prodotto:
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