We report the first example of a reversible redox-molecular switch based on dipolar ruthenium(III/II) pentaammine(4,4′-bipyridinium) complexes self-assembled on an optically transparent metal electrode, whose change in molecular properties can be simply detected by transmission spectroscopy with a conventional spectrophotometer.
Novel self-assembled monolayers of dipolar Ruthenium(III/II) pentaammine (4,4'-bipyridinium) complexes on ultrathin platinum films as redox molecular switches
SORTINO, Salvatore;Petralia S;DI BELLA, Santo
2003-01-01
Abstract
We report the first example of a reversible redox-molecular switch based on dipolar ruthenium(III/II) pentaammine(4,4′-bipyridinium) complexes self-assembled on an optically transparent metal electrode, whose change in molecular properties can be simply detected by transmission spectroscopy with a conventional spectrophotometer.File in questo prodotto:
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