The very large cation-anion environmental effects on second-order nonlinear optical response observed in self-assembled stilbazolium monolayer ion-exchange experiments are investigated theoretically using the ZINDO/SOS quantum chemical formalism. Ion pairs consisting of the 4'-(dimethylamino)-N-methyl-4-stilbazolium cation with chloride, iodide, and p-aminobenzenesulfonate counteranions in differing mutual orientations, are examined as models to relate calculated ion pair hyperpolarizabilities to anion-exchange-induced changes in macroscopic linear optical and nonlinear optical response. Calculated hyperpolarizabilities depend strongly on the relative cation-anion packing configuration. In accord with anion exchange experiments, enhancements of the second-order nonlinear optical response on passing from Cl- to I- and p-aminobenzenesulfonate can be related to likely displacement of the bulkier I- and p-aminobenzenesulfonate anions from more closely packed structural arrangements originally produced as a consequence of the self-assembly process.
CHROMOPHORE ENVIRONMENTAL-EFFECTS IN SALTLIKE NONLINEAR-OPTICAL MATERIALS - A COMPUTATIONAL STUDY OF ARCHITECTURE ANION 2ND-ORDER RESPONSE RELATIONSHIPS IN HIGH-BETA STILBAZOLIUM SELF-ASSEMBLED FILMS
DI BELLA, Santo;
1995-01-01
Abstract
The very large cation-anion environmental effects on second-order nonlinear optical response observed in self-assembled stilbazolium monolayer ion-exchange experiments are investigated theoretically using the ZINDO/SOS quantum chemical formalism. Ion pairs consisting of the 4'-(dimethylamino)-N-methyl-4-stilbazolium cation with chloride, iodide, and p-aminobenzenesulfonate counteranions in differing mutual orientations, are examined as models to relate calculated ion pair hyperpolarizabilities to anion-exchange-induced changes in macroscopic linear optical and nonlinear optical response. Calculated hyperpolarizabilities depend strongly on the relative cation-anion packing configuration. In accord with anion exchange experiments, enhancements of the second-order nonlinear optical response on passing from Cl- to I- and p-aminobenzenesulfonate can be related to likely displacement of the bulkier I- and p-aminobenzenesulfonate anions from more closely packed structural arrangements originally produced as a consequence of the self-assembly process.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
