A new series of supramolecular assemblies is obtained through the interaction of 3-pyridylmethyl-calixarenes and copper or zinc ions. The complexes formed are characterized both in solution and in the solid state. The results offer appealing insights into how the steric crowding of the lower rim and different coordination modes of the metal centers have a great impact on the overall architecture of the complexes with the formation of monomeric, dimeric, or oligomeric/polymeric species.
Titolo: | Three-dimensional network structures based on pyridylcalix[4]arene metal complexes |
Autori interni: | |
Data di pubblicazione: | 2017 |
Rivista: | |
Handle: | http://hdl.handle.net/20.500.11769/314529 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.