Mesitonitrile oxide adds to polycyclic aromatic compounds (PACs) such as phenanthrene and pyrene to give mono-cycloadducts. Pyrene does not afford bis-cycloadducts even when a large excess of 1,3-dipole is used. The more reactive benzonitrile oxide does not react with these PACs.
Dipolarophilic reactivity of polycyclic aromatic compounds towards nitrile oxides
CHIACCHIO, Ugo;
1996-01-01
Abstract
Mesitonitrile oxide adds to polycyclic aromatic compounds (PACs) such as phenanthrene and pyrene to give mono-cycloadducts. Pyrene does not afford bis-cycloadducts even when a large excess of 1,3-dipole is used. The more reactive benzonitrile oxide does not react with these PACs.File in questo prodotto:
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