Host–guest complexes of an amphiphilic watersolublep-tert-butylcalix[5]arene bearing 4-sulphonatobutoxygroups at the narrow rim with trace amines (2-phenylethylamine and tyramine) and a neurotransmitter (dopamine), originally investigated via 1H NMR, have been re-examined via ITC in order to double check the reliability of the values obtained through a van’t Hoff analysis of the NMR data. The calorimetrically determineddata confirm the existence of a 1:1 host–guest species;however, there are inconsistencies between the van’t Hoff derived values and the values determined via direct calorimetry. These discrepancies do not result from proton displacement due to inclusion, but rather result from the temperature dependence of the van’t Hoff enthalpies.
Complexation of biologically active amines by a water-soluble calix[5]arene. A nanocalorimetric investigation
ARENA, Giuseppe;PAPPALARDO, ANDREA;SGARLATA, CARMELO
2015-01-01
Abstract
Host–guest complexes of an amphiphilic watersolublep-tert-butylcalix[5]arene bearing 4-sulphonatobutoxygroups at the narrow rim with trace amines (2-phenylethylamine and tyramine) and a neurotransmitter (dopamine), originally investigated via 1H NMR, have been re-examined via ITC in order to double check the reliability of the values obtained through a van’t Hoff analysis of the NMR data. The calorimetrically determineddata confirm the existence of a 1:1 host–guest species;however, there are inconsistencies between the van’t Hoff derived values and the values determined via direct calorimetry. These discrepancies do not result from proton displacement due to inclusion, but rather result from the temperature dependence of the van’t Hoff enthalpies.File | Dimensione | Formato | |
---|---|---|---|
J. Therm. Anal. Calorim. 2015, 121, 1073-1079.pdf
solo gestori archivio
Tipologia:
Versione Editoriale (PDF)
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
843.81 kB
Formato
Adobe PDF
|
843.81 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.