A polysiloxane diglycidyl ether was used as a comonomer of epoxy resins to obtain coatings through the ultraviolet curing technique. Notwithstanding its very low concentration (<1 wt %), the siloxane monomer caused a change in the surface properties of the films. Selective surface stratification was evidenced by X-ray photoelectron spectroscopy analysis, and an interesting surface modification was achieved without changing the bulk properties of the films or the rate of polymerization.
Surface properties of cationic ultraviolet-curable coatings containing a siloxane structure
POLLICINO, Antonino;RECCA, Antonino;
2004-01-01
Abstract
A polysiloxane diglycidyl ether was used as a comonomer of epoxy resins to obtain coatings through the ultraviolet curing technique. Notwithstanding its very low concentration (<1 wt %), the siloxane monomer caused a change in the surface properties of the films. Selective surface stratification was evidenced by X-ray photoelectron spectroscopy analysis, and an interesting surface modification was achieved without changing the bulk properties of the films or the rate of polymerization.File in questo prodotto:
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