A polysiloxane diglycidyl ether was used as a comonomer of epoxy resins to obtain coatings through the ultraviolet curing technique. Notwithstanding its very low concentration (<1 wt %), the siloxane monomer caused a change in the surface properties of the films. Selective surface stratification was evidenced by X-ray photoelectron spectroscopy analysis, and an interesting surface modification was achieved without changing the bulk properties of the films or the rate of polymerization.

Surface properties of cationic ultraviolet-curable coatings containing a siloxane structure

POLLICINO, Antonino;RECCA, Antonino;
2004-01-01

Abstract

A polysiloxane diglycidyl ether was used as a comonomer of epoxy resins to obtain coatings through the ultraviolet curing technique. Notwithstanding its very low concentration (<1 wt %), the siloxane monomer caused a change in the surface properties of the films. Selective surface stratification was evidenced by X-ray photoelectron spectroscopy analysis, and an interesting surface modification was achieved without changing the bulk properties of the films or the rate of polymerization.
2004
Cationic polymerization; Polysiloxanes; Surfaces
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/34743
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