The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favourable and fully non-covalent long-range electronic communication.
Long-Range Chiral Induction by a Fully Non-Covalent Approach in Supramolecular Porphyrin-Calixarene Assemblies†
Gaeta, Massimiliano;Sortino, Giuseppe;Randazzo, Rosalba;Fragalà, Maria Elena;D'Urso, Alessandro
;Purrello, Roberto
2020-01-01
Abstract
The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favourable and fully non-covalent long-range electronic communication.File in questo prodotto:
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