For the first time, the tetrafluorobenzyl unit has been considered as a C-H⋯anion binding motif. In synergy with imidazolium groups within a bowl-shaped receptor, it has allowed for the effective binding of chloride in solution. Remarkable affinity was observed in organic-water mixtures.
|Titolo:||Chloride-binding in organic-water mixtures: The powerful synergy of C-H donor groups within a bowl-shaped cavity|
|Data di pubblicazione:||2016|
|Appare nelle tipologie:||1.1 Articolo in rivista|