Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.

Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.

6‐Deoxy‐6‐N‐histamino‐β‐cyclodextrin Copper(II) Complex, a New Enantioselective Receptor for Aromatic Amino Acids

RIZZARELLI, Enrico;VECCHIO G;
1991-01-01

Abstract

Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.
Chiral recognition of D- and L-tryptophan in the mobile phase in the presence of the title complex [CuL]2+ is the reason for their successful HPLC separation on a conventional achiral reversed-phase column. The separation is based on mixed inclusion-ligand-exchange chromatography, in which the more stable complex [CuL(D-Trp)]+ probably has the form shown here.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/41213
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