CD and UV-vis measurements were carried out to demonstrate chirality induction-promoted by chiral covalently linked groups and non-covalently bound Delta-and Lambda-[Ru(phen)(3)](2+) enantiomers-in metallo-porphyrin-calixarene and metallo-porphyrin-bis-calixarene non-covalent assemblies, respectively.
CD and UV-vis measurements were carried out to demonstrate chirality induction-promoted by chiral covalently linked groups and non-covalently bound Delta-and Lambda-[Ru(phen)(3)](2+) enantiomers-in metallo-porphyrin-calixarene and metallo-porphyrin-bis-calixarene non-covalent assemblies, respectively.
Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach
D'URSO, ALESSANDRO;FRAGALA', Maria Elena;PAPPALARDO, ANDREA;PURRELLO, Roberto
2012-01-01
Abstract
CD and UV-vis measurements were carried out to demonstrate chirality induction-promoted by chiral covalently linked groups and non-covalently bound Delta-and Lambda-[Ru(phen)(3)](2+) enantiomers-in metallo-porphyrin-calixarene and metallo-porphyrin-bis-calixarene non-covalent assemblies, respectively.File in questo prodotto:
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