Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol
BALLISTRERI, Francesco Paolo;PAPPALARDO, ANDREA;TOMASELLI, Gaetano;TOSCANO, Rosa Maria;TRUSSO SFRAZZETTO, GIUSEPPE
2016-01-01
Abstract
Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).File in questo prodotto:
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Int. J. Mol. Sci. 2017, 17, 1112.pdf
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