Cost-effective and efficient photoelectrochemical (PEC) water splitting stands out as one of the most promising strategies to address sustainable energy supply in the form of green H2. Large-area photoelectrodes featuring precise chemical and morphological control are key components for a practical solar-to-hydrogen conversion. Herein, we report the continuous flow synthesis of BiVO4 nanoparticles (NPs) by using a simple microreactor configuration. The solution containing the as-prepared NPs enables the deposition of BiVO4 photoanodes with areas up to 52 cm2 through a simple and scalable chemical bath deposition method. On the other hand, surface protection by an ultrathin Al2O3 overlayer grown by atomic layer deposition (ALD) increases the performance of the 1 cm2 BiVO4 photoanodes ~30 %, exhibiting a photocurrent density of ~2.0 mA⋅cm−2 at 1.23 V vs. the Reversible Hydrogen Electrode in the presence of a sacrificial hole scavenger. The optimized continuous flow synthesis provides an affordable methodology for the fabrication of cost-effective, large-scale photoanodes, which could potentially be applied for different photoelectrochemical reactions.
Continuous‐Flow Synthesis of BiVO4 Nanoparticles: From Laboratory Scale to Practical Systems
Maria Chiara Spadaro;
2025-01-01
Abstract
Cost-effective and efficient photoelectrochemical (PEC) water splitting stands out as one of the most promising strategies to address sustainable energy supply in the form of green H2. Large-area photoelectrodes featuring precise chemical and morphological control are key components for a practical solar-to-hydrogen conversion. Herein, we report the continuous flow synthesis of BiVO4 nanoparticles (NPs) by using a simple microreactor configuration. The solution containing the as-prepared NPs enables the deposition of BiVO4 photoanodes with areas up to 52 cm2 through a simple and scalable chemical bath deposition method. On the other hand, surface protection by an ultrathin Al2O3 overlayer grown by atomic layer deposition (ALD) increases the performance of the 1 cm2 BiVO4 photoanodes ~30 %, exhibiting a photocurrent density of ~2.0 mA⋅cm−2 at 1.23 V vs. the Reversible Hydrogen Electrode in the presence of a sacrificial hole scavenger. The optimized continuous flow synthesis provides an affordable methodology for the fabrication of cost-effective, large-scale photoanodes, which could potentially be applied for different photoelectrochemical reactions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
