This study explores the feasibility of utilizing granite sawing sludge (FC) as a precursor to produce alkali-activated materials (AAMs). To enhance the reactivity of the system, metakaolin (MK) was added and binary mixtures were synthetized. A multidisciplinary approach, including mineralogical, chemical and mechanical analysis, was employed to assess the suitability of these precursors to produce AAMs. X-Ray diffraction (XRD) and Fourier-Transform Infrared spectroscopy (FT-IR) confirmed the occurred activation reaction with the consequent increase in the amorphous content. Raman spectroscopy was used to further explore the mineralogical composition of the consolidated specimens, helping in the detection of salts, whose formation is ascribed to secondary carbonatation processes. Morphological analysis (SEM-EDS) displayed relatively uniform microstructures for all specimens. Compressive strength tests revealed that MK rich samples achieved best values compared to FC rich formulations, which exhibited reduced strength resistance. This study highlights, for the first time, the benefits of incorporating Cuasso al Monte granite sawing sludges into alkali-activated binders. Results suggested that the incorporation of FC is recommended for both environmental and economic advantages.

Exploring the Potential of Granite Sawing Sludge from Cuasso Al Monte (Italy) for the Development of Aluminosilicate Gel for a Sustainable Industry

Sabrina Elettra Zafarana
Primo
;
Germana Barone
;
Claudio Finocchiaro;Silvia Portale;Paolo Mazzoleni
Ultimo
2025-01-01

Abstract

This study explores the feasibility of utilizing granite sawing sludge (FC) as a precursor to produce alkali-activated materials (AAMs). To enhance the reactivity of the system, metakaolin (MK) was added and binary mixtures were synthetized. A multidisciplinary approach, including mineralogical, chemical and mechanical analysis, was employed to assess the suitability of these precursors to produce AAMs. X-Ray diffraction (XRD) and Fourier-Transform Infrared spectroscopy (FT-IR) confirmed the occurred activation reaction with the consequent increase in the amorphous content. Raman spectroscopy was used to further explore the mineralogical composition of the consolidated specimens, helping in the detection of salts, whose formation is ascribed to secondary carbonatation processes. Morphological analysis (SEM-EDS) displayed relatively uniform microstructures for all specimens. Compressive strength tests revealed that MK rich samples achieved best values compared to FC rich formulations, which exhibited reduced strength resistance. This study highlights, for the first time, the benefits of incorporating Cuasso al Monte granite sawing sludges into alkali-activated binders. Results suggested that the incorporation of FC is recommended for both environmental and economic advantages.
2025
alkali-activated materials
composite materials
mining waste
upcycling
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/687069
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 0
social impact