Title 1,3-dipoles add to phenanthrene, pyrene, anthracene and perylene, but not to naphthalene and triphenylene, to give a regioisomeric monocycloadduct. Anthracene give also the two corresponding biscycloadducts. The site- and regio-selectivity of the reactions of the anthracene and pyrene is discussed in terms of FMO approximation. Copyright (C) 1996 Published by Elsevier Science Lid
1,3-dipolar cycloaddition reactions of polycyclic aromatic hydrocarbons with 3,5-dichloro-2,4,6-trimethyl- and 2,4,6-trimethylbenzonitrile oxide.
CHIACCHIO, Ugo;PISTARA', Venerando
1996-01-01
Abstract
Title 1,3-dipoles add to phenanthrene, pyrene, anthracene and perylene, but not to naphthalene and triphenylene, to give a regioisomeric monocycloadduct. Anthracene give also the two corresponding biscycloadducts. The site- and regio-selectivity of the reactions of the anthracene and pyrene is discussed in terms of FMO approximation. Copyright (C) 1996 Published by Elsevier Science LidFile in questo prodotto:
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