Electrochemical Impedance Spectroscopy (EIS) is a widely used technique for characterizing the electrode–electrolyte interface. EIS analysis can be very complex and tedious. In this work, a fitting algorithm written in C is implemented on OriginPro software to avoid the data import/export operation and speed up the analysis. An automated fitting procedure that assigns the initial parameters is implemented for the simplest equivalent circuit. In addition, the possibility of using a custom error function is explored, with results comparable to that of reference software. The developed algorithm is tested on two different case studies.

Computational Approach to Fast Analysis of Electrochemical Impedance Spectroscopy

Cristiano Lo Po'
Primo
;
Stefano Boscarino
;
Francesco Ruffino
2026-01-01

Abstract

Electrochemical Impedance Spectroscopy (EIS) is a widely used technique for characterizing the electrode–electrolyte interface. EIS analysis can be very complex and tedious. In this work, a fitting algorithm written in C is implemented on OriginPro software to avoid the data import/export operation and speed up the analysis. An automated fitting procedure that assigns the initial parameters is implemented for the simplest equivalent circuit. In addition, the possibility of using a custom error function is explored, with results comparable to that of reference software. The developed algorithm is tested on two different case studies.
2026
EIS
fitting algorithm
gradient descent
Powell algorithm
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/721741
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