Developing sustainable energy storage devices is challenging for the progress of energy storage applications. Here, nanotechnology represents a strategic route to reduce the amount of used critical materials, while continuing to take advantage of their properties, thanks to the high surface to volume ratio which characterizes nanostructures. WO3 3 nanostructures represent a promising active material for energy storage applications, thanks to their wide capability of small positive ions (H+ + and Li+) + ) intercalation and their high stability in acidic conditions. The coupling between WO3 3 nanorods and carbon black powder is studied to realize a highly efficient coin cell supercapacitor. The morphology of WO3 3 nanorods and carbon black is investigated by using a scanning electron microscope, and the energy storage performances were evaluated by performing cycling voltammetry and galvanostatic charge and discharge analysis, thus obtaining promising specific capacitance results (79 and 70 F/g at 5 mV/s and 0.5 A/g respectively). Moreover, the stability of the obtained coin cell was investigated, thus getting good capacity retention over 250 charge-discharge cycles. Energy and power densities were also calculated, obtaining the highest energy density of 39 Wh/kg at a power density of 500 W/kg. The WO3-carbon 3 - carbon black coin cells are used to power a red LED, so demonstrating the viability for practical applications.

Facile preparation of a highly efficient coin cell supercapacitor based on WO3 nanorods

Mineo Giacometta
Writing – Original Draft Preparation
;
Ursino Federico
Data Curation
;
Terrasi Antonio
Writing – Review & Editing
;
Bruno Elena
Writing – Review & Editing
;
Mirabella Salvatore
Supervision
2024-01-01

Abstract

Developing sustainable energy storage devices is challenging for the progress of energy storage applications. Here, nanotechnology represents a strategic route to reduce the amount of used critical materials, while continuing to take advantage of their properties, thanks to the high surface to volume ratio which characterizes nanostructures. WO3 3 nanostructures represent a promising active material for energy storage applications, thanks to their wide capability of small positive ions (H+ + and Li+) + ) intercalation and their high stability in acidic conditions. The coupling between WO3 3 nanorods and carbon black powder is studied to realize a highly efficient coin cell supercapacitor. The morphology of WO3 3 nanorods and carbon black is investigated by using a scanning electron microscope, and the energy storage performances were evaluated by performing cycling voltammetry and galvanostatic charge and discharge analysis, thus obtaining promising specific capacitance results (79 and 70 F/g at 5 mV/s and 0.5 A/g respectively). Moreover, the stability of the obtained coin cell was investigated, thus getting good capacity retention over 250 charge-discharge cycles. Energy and power densities were also calculated, obtaining the highest energy density of 39 Wh/kg at a power density of 500 W/kg. The WO3-carbon 3 - carbon black coin cells are used to power a red LED, so demonstrating the viability for practical applications.
2024
Tungsten oxide
Energy storage
Coin cell
Supercapacitors
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11769/634349
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